The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Aromatic compounds / Aldehydes / C6H5CHO / IUPAC(2021)_298K_220-395nm(rec)

DATAFILE: C6H5CHO_IUPAC(2021)_298K_220-395nm(rec).txt
NAME: benzaldehyde
FORMULA: C6H5CHO
AUTHOR(YEAR): IUPAC(2021)
T: 298K
λ: 220-395nm(rec)
BIBLIOGRAPHY: A. Mellouki, M. Ammann, R. A. Cox, J. N. Crowley, H. Herrmann, M. E. Jenkin, F. McNeill, J. Troe, and T. J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: volume VIII – gas-phase reactions of organic species with four, or more, carbon atoms ( ≥  C4)", Atmos. Chem. Phys. 21, 4797–4808 (2021); DOI: 10.5194/acp-21-4797-2021
COMMENTS: IUPAC(2021) recommendation:

220-250 nm, data of

G. El Dib, A. Chakir, E. Roth, J. Brion, and D. Daumont, "Study of benzylperoxy radical using laser photolysis: Ultraviolet spectrum, self-reaction, and reaction with HO2 kinetics," J. Phys. Chem. A 110, 7848-7857 (2006); DOI: 10.1021/jp056860p,

255-290nm, mean of the data of

T. Etzkorn, B. Klotz, S. Sørensen, I.V. Patroescu, I. Barnes, K.H. Becker, and U. Platt, "Gas-phase absorption cross sections of 24 monocyclic aromatic hydrocarbons in the UV and IR spectral ranges," Atmos. Environ. 33, 525-540 (1999); DOI: 10.1016/S1352-2310(98)00289-1,

G. Thiault, A. Mellouki, G. Le Bras, A. Chakir, N. Sokolowski-Gomez, and D. Daumont, "UV-absorption cross sections of benzaldehyde, ortho-, meta-, and para-tolualdehyde," J. Photochem. Photobiol. A: Chem. 162, 273-281 (2004); DOI: 10.1016/j.nainr.2003.08.012, and

G. El Dib, A. Chakir, E. Roth, J. Brion, and D. Daumont, "Study of benzylperoxy radical using laser photolysis: Ultraviolet spectrum, self-reaction, and reaction with HO2 kinetics," J. Phys. Chem. A 110, 7848-7857 (2006); DOI: 10.1021/jp056860p,

295-395 nm, mean of the data of

G. Thiault, A. Mellouki, G. Le Bras, A. Chakir, N. Sokolowski-Gomez, and D. Daumont, "UV-absorption cross sections of benzaldehyde, ortho-, meta-, and para-tolualdehyde," J. Photochem. Photobiol. A: Chem. 162, 273-281 (2004); DOI: 10.1016/j.nainr.2003.08.012,
(blue shifted by 4 nm between 335 and 375nm),

B. Xiang, C. Zhu, and L. Zhu, "Gas-phase absorption cross sections of 2-nitrobenzaldehyde and benzaldehyde in the 285-400 nm region, and photolysis of 2-nitrobenzaldehyde vapor at 308 and 351 nm," Chem. Phys. Lett. 474, 74-78 (2009); DOI: 10.1016/j.cplett.2009.04.056, and

J. Chen, J.C. Wenger, and D.S. Venables, "Near-ultraviolet absorption cross sections of nitrophenols and their potential influence on tropospheric oxidation capacity," J. Phys. Chem. A 115, 12235-12242 (2011); DOI: 10.1021/jp206929r

in the regions of overlap

Error in the table heading corrected: 1018σ/cm2 instead of 1020σ/cm2

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